Group 2 Mediated Dehydrocoupling
Liptrot, David J
Produktnummer:
18d65169d596ff486a988f4f6786783537
| Autor: | Liptrot, David J |
|---|---|
| Themengebiete: | Boron-nitrogen dehydrocoupling Group 2 Hydrogen storage S-block hydrides Sigma-bond metathesis Silicon-nitrogen dehydrocoupling Single electron transfer |
| Veröffentlichungsdatum: | 07.08.2015 |
| EAN: | 9783319210353 |
| Sprache: | Englisch |
| Seitenzahl: | 162 |
| Produktart: | Gebunden |
| Verlag: | Springer International Publishing |
Produktinformationen "Group 2 Mediated Dehydrocoupling"
This book presents an in-depth study into the utility of s-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner. Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with s-bond metathesis allows a novel hydrogen release from silanes.
Sie möchten lieber vor Ort einkaufen?
Sie haben Fragen zu diesem oder anderen Produkten oder möchten einfach gerne analog im Laden stöbern? Wir sind gerne für Sie da und beraten Sie auch telefonisch.
Juristische Fachbuchhandlung
Georg Blendl
Parcellistraße 5 (Maxburg)
8033 München
Montag - Freitag: 8:15 -18 Uhr
Samstags geschlossen