Design, Synthesis and Characterization of new Supramolecular Architectures
Baroncini, Massimo
Produktnummer:
18654271f34dda4133a7c2c35021fa6bec
| Autor: | Baroncini, Massimo |
|---|---|
| Themengebiete: | Molecular Logic Nanotechnology Rotaxanes Chemistry Supramolecular Chemistry Viologen Dendrimers |
| Veröffentlichungsdatum: | 20.04.2011 |
| EAN: | 9783642192845 |
| Sprache: | Englisch |
| Seitenzahl: | 90 |
| Produktart: | Gebunden |
| Verlag: | Springer Berlin |
Produktinformationen "Design, Synthesis and Characterization of new Supramolecular Architectures"
This thesis focuses on the bottom-up design, construction and operation of supramolecular systems capable of behaving as devices and machines on the molecular scale, which is a topic of great interest in nanoscience and a fascinating challenge in nanotechnology. In particular, the systems investigated here include: polyviologen dendrimers capable of behaving as hosts and chargestoring devices; molecular machines based on pseudorotaxanes/rotaxanes and operated by photoinduced proton transfer, or photoisomerization reactions; and a simple unimolecular multiplexer/demultiplexer. The systems have been characterized using a variety of techniques including absorption and emission spectra, laser flash photolysis, NMR spectroscopy, electrochemical experiments, stopped flow measurements. This research addresses a large number of open problems in the nanosciences, dealing with a wide range of the most advanced applications of supramolecular systems.
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